The Manufacture of Perchlorate by Direct Method Using Graphite Substrate Lead Dioxide (Gsld) Anode
Keywords:
Perchlorate, Lead dioxide anode, GSLD anode, Direct oxidation of sodium chlorideAbstract
Sodium perchlorate has been prepared electrochemically from sodium chloride solutions in one step by passing a direct current through the solution , in the presence of certain addition agents (like sodium fluoride). A laboratory electrolytic cell has been designed to obtain experimental results for the preparation of sodium perchlorate. A solution of sodium chloride (290 g/l ) and sodium fluoride (2 g/l ) is electrolyzed in a batch wise. A stainless steel cathode and Graphite substrate lead dioxide (GSLD) anode are satisfactory . The influence of anodic current density , temperature ,and pH of electrolyte on current efficiency of sodium perchlorate formation were studied. The current efficiency of about 68% was obtained by using (GSLD) anode
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Copyright (c) 2009 Ahmed D. Wiheeb
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