Study the Effect of Glycols Base Cosolvent Additives on Breaking of Crude Oil Emulsion

https://doi.org/10.24237/djes.2010.03204

Authors

  • Adel Sharif Hamadi Department of Chemical Engineering, University of Technology.

Keywords:

Demulsification efficiency, w/o emulsion breaking, glycol base surfactants

Abstract

Emulsion breaking is one of complex process used in many practical applications such as the petroleum industry, painting and waste-water treatment in environmental technology. Chemical demulsification is the most widely resolved method of treating water-in-crude oil emulsions and involves the addition of chemical reagents to destroy the protective action of emulsifying agents and allow accelerating the emulsion breaking process. Our experimental results showed that, the addition of glycols chemicals as a cosolvents like ethylene glycol methyl ether (EGME), monoethylene glycol (MEG), polyethylene glycol (PEG-1500), in combination with commercial demulsifier RP-6000 will enhancing the process of emulsion demulsification. The demulsification experiments were carried out at controlled temperature 65oC and screened by bottle test using about 100 ppm demulsifier doses. The maximum amount of water separated after 120 min found to be 87.7% for (75/25) (RP6000/PEG1500) .Where, the water separations for (75/25) (RP6000/MEG) and (75/25) (RP6000/EGME) for demulsifier were 71% and 65.2% respectively

Downloads

Download data is not yet available.

References

- Steinhauff, F., (1962), "Modern Oilfield Demulsification. Part I" Petroleum. vol. 25, 294-296.

- Bhardwaj, A. and Hartland, S., (1998), "Studies on Build up of Interfacial Film at the Crude Oil/Water Interface", J. Dis. Sci. Tech., Vol 19, No.4, 465-473.

- Selvarajan Radhakrisnan, Anantha-subramaniam Sivakumar and Robert A. M., (2001), "Aqueous Dispersion of an Oil Soluble Demulsifier for Breaking Crude Oil Emulsions", US Patent No. 6,294,093.

- Mohammed, R. A., Bailey, A. I., Luckham. P. F. Taylor, S. E., (1993), "Dewatering of crude oil emulsions. 1. Rheological behaviors of crude oil-water interface", Colloids and surface,Vol 80, pp 223-235.

- Kim. B. Y., Moon. J. H. Sung. T. H., Yang, S. M., Kim, J. D., (2002), "Demulsification of water in crude oil emulsions by a continuous electrostatic dehydrator", Separation Science and Technology, Vol 37, No.6, pp 1307-1320.

- Cormack D., (1999), “Response to marine oil pollution - Review and assessment", Vol.2, Kluwer Academic Publishers.

- Adel Sh. Hamadi, Luma H. Mahmood, (2010), “Demulsifiers for Simulated Basrah Crude Oil” Eng. and Tech J., Vol 28, No.1, pp 54-64.

- Poindexter, M. K., Lindemuth. P. M., (2004), "Applied statistics: Crude oil emulsions and demulsifiers", Journal of Dispersion Science & Technology Vol. 25, No. 3, pp 311-320.

- Nordvik, A. B., Simmons, J. L. Bitting. K. R., Levis, A., Kristiansen, T. S., (1996), "Oil and water separation in marine oil spill clean-up operations", Spill science & Technology, Vol 3, No. 3, 107-122.

- Auflem, I. H., (2002), "Influence of Asphalting Aggregation and Pressure on Crude Oil Emulsion Stability", Ph.D., Thesis, Norwegian University of Science and Technology.

- Aurelle Y., Bonnet J., Roques H. and Ver A., (1978), “Hydrophilic Silicone Elastomer Material Used in Particular for Impression”, French Patent 2,368,505.

- Vogel P. W., (1979), “Acylated polyoxyalkylene polyamines”, U. S. Patent 4,151,173.

- Amaravathi M. and Pandey B. P., (1991), “Chemically Induced Destabilization of Water-in-Crude Oil Emulsions”, Res. Ind., Vol. 36, No. 198.

- Berkhof R., Kwekkeboom H., Dieter B.and Ripke N., (1992), European Patent 468,095.

- Wigand G., Joachim H., Richter B.and Koch B., (1992), German Patent 298,805.

- Nael N. Zaki, Manar E. Abdel-Raouf and Abdel-Azim A. Abdel-Azim., (1996), "Propylene Oxide-Ethylene Oxide Block Copolymers as Demulsifiers for Water-in-Oil Emulsions. I. Effect of Molecular Weight and Hydrophilic - Lipophylic Balance (HLB) on the Demulsification Efficiency”, Monatshefte Fur Chemie (Chemical Monthly) of Austria, 127, 621.

- Schramm, L. L., (1992), "Petroleum Emulsion", In.: Schramm, L. L., "Emulsions Fundamentals and Applications in the Petroleum Industry", American Chemical Society, Washington DC., pp 1-45.

- Fiocco, J.R. and Lewis, A., (1999), "Oil Spill Dispersants". Pure Appl. Chem. Vol. 71, No. 1, pp 27–42.

- Adel SH. Hamadi, Hamidillin R. F., Shibayva, O. N., Diyarov E. E., (2003) ,“New Composition of Chemical Reagents for Improvement the Rheological Properties for Heavy Crude Oils”, (in Russian), Science and Technology of Hydrocarbon, Moscow, Vol. 28, No. 4, pp 24-29.

- Karsa, D. R., (1992), "Industrial application of surfactants III ", the Royal society of chemistry.

- Lissant, K. J., (1983), "Demulsification Industrial Applications, Marcel Dekker, NewYork, pp 119.

- Chod T.J., (1996),"Surfactants / Cosolvents", Technology Evaluation Report, GWRTAC series.

- Martin E. W., (1971) "Dispensing of Medication," 7th ed., Mack Publishing Co., Easton, Pa., p. 831.

Published

2010-12-01

How to Cite

[1]
Adel Sharif Hamadi, “Study the Effect of Glycols Base Cosolvent Additives on Breaking of Crude Oil Emulsion”, DJES, vol. 3, no. 2, pp. 42–52, Dec. 2010.